Studying the impact of precipitation on PM2.5 mass concentration in different regions can provide an important scientific support for the air quality assessment and forecast as well as pollution prevention in this region. Based on the hourly precipitation observation data and PM2.5 mass concentration monitoring data in five typical cities (Chengdu, Leshan, Yibin, Mianyang and Dazhou) of Sichuan Basin from 2016 to 2021, the scavenging effect of precipitation processes on PM2.5 was analyzed in different cities from some aspects including the occurrence time, duration, intensity of precipitation and the initial mass concentration of PM2.5. The results show that the proportion of positive scavenging processes of precipitation on PM2.5 increases with the increase of precipitation intensity or initial mass concentration of PM2.5 in Sichuan Basin, and the scavenging rate rises. Under the condition of air pollution, the scavenging effect of precipitation with intensity exceeding 1 mm·h-1 on PM2.5 improves obviously in Sichuan Basin, and the scavenging rate reaches 35.0%. The scavenging effect is positively correlated with the duration of precipitation processes, and the scavenging rate of precipitation processes with the duration more than 3 hours is 9.0%-18.0% higher than that of precipitation processes with the duration less than or equal to 3 hours. The probability of positive scavenging processes is higher in the early morning and afternoon in Sichuan Basin, and the precipitation processes in the early morning have better scavenging effect on PM2.5. In comparison, the proportion of positive scavenging processes is higher in Leshan and Yibin after the precipitation, and under different initial mass concentrations of PM2.5, the scavenging rate is significantly higher than that in other cities with the increase of precipitation duration.